nznistuНауки о Земле и недропользованиеEarth sciences and subsoil use2686-99932686-7931Federal State Budget Educational Institution of Higher Education "Irkutsk National Research Technical University"10.21285/2686-9993-2021-44-2-167-173nznistu-144Research ArticleСтатьиИдентификация природных и техногенных процессов в подземной гидросфере на основе анализа полиареновPolyarene analysis-based identification of natural and technogenic processes in underground hydrospherehttps://orcid.org/0000-0002-5338-3960ХаустовА. П.KhaustovA. P.

Хаустов Александр Петрович, доктор геолого-минералогических наук, профессор, профессор кафедры прикладной экологии

117198, г. Москва, ул. Миклухо-Маклая, 6

Alexander P. Khaustov, Dr. Sci. (Geol. & Mineral.), Professor, Professor of the Department of Applied Ecology, RUDN University

6 Miklukho-Maklaya St., Moscow 117198

khaustov-ap@rudn.ruhttps://orcid.org/0000-0002-3169-0142РединаМ. М.RedinaM. M.

Редина Маргарита Михайловна, доктор экономических наук, доцент, заведующая кафедрой прикладной экологии

117198, г. Москва, ул. Миклухо-Маклая, 6

Margarita M. Redina, Dr. Sci. (Econ.), Associate Professor, Head of the Department of Applied Ecology, RUDN University

6 Miklukho-Maklaya St., Moscow 117198

redina-mm@rudn.ruРоссийский университет дружбы народовРоссияRUDN UniversityRussian Federation202116062021442167173Copyright © Хаустов А.П., Редина М.М., 20212021Хаустов А.П., Редина М.М.Khaustov A.P., Redina M.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.nznj.ru/jour/article/view/144

Цель работы заключалась в анализе возможности идентификации генезиса загрязнений подземной гидросферы на основе данных о полиаренах как геохимических маркерах. Маркерная роль обусловлена токсичностью, стойкостью, привязкой этих веществ к конкретным источникам загрязнения и процессам в природе и техносфере. Основным методом исследования являлся анализ индикаторных соотношений полиаренов. Объектом исследования служили подземные воды разных регионов мира, загрязненные природными и антропогенными полиаренами. В результате авторами показаны основные направления отечественных и зарубежных исследований и освещены проблемы их проведения. C применением индикаторных соотношений успешно распознаны пирогенно и петрогенно загрязненные пробы подземных вод и продемонстрированы примеры изучения полиаренов как геохимических маркеров. Установлено, что полиарены являются эффективным индикатором генезиса загрязнений подземной гидросферы. Тем не менее их анализ требует применения современных методов отбора, подготовки проб, экстракции, что значительно осложняет исследования на практике.

The purpose of the study is to analyze the possibility to identify the pollution genesis of the underground hydrosphere based on the data on polyarenes as geochemical markers. Their marker role is due to their toxicity, persistence and confinement to specific pollution sources and natural and technogenic processes. The main research method is the analysis of indicator ratios of polyarenes. The object of research is groundwater from different regions of the world, which are polluted by natural and anthropogenic polyarenes. The main directions of domestic and foreign researches as well as the problems of their implementation are shown. The use of indicator ratios enabled successful identification of pyro- and petrogenically polluted samples of groundwater also the examples of the study of polyarenes as geochemical markers were demonstrated. The polyarenes are shown to be an effective indicator of the pollution genesis in the underground hydrosphere. However, their analysis requires the use of modern methods of sampling, sample preparation and extraction, which significantly complicates research in practice.

подземная гидросфераподземные водыполициклические ароматические углеводородытехногенеззагрязнениеunderground hydrospheregroundwaterpolycyclic aromatic hydrocarbonstechnogenesispollutionРабота выполнена при поддержке Программы стратегического академического лидерства Российского университета дружбы народов.The research was supported by the Strategic Academic Leadership Program of the Peoples' Friendship University of Russia (RUDN).ReferencesMattox C.F., Humenick M.J. Organic groundwater contaminants from UCG // Proceedings of the 5th Underground Coal Conversion Symposium. Alexandria, 1979.Mattox CF, Humenick MJ. Organic groundwater contaminants from UCG. In: Proceedings of the 5th Underground Coal Conversion Symposium. Alexandria; 1979.Richard D.E., Dwyer D.F. Aerated biofiltration for simultaneous removal of iron and polycyclic aromatic hydrocarbons from groundwater // Water Environment Research. 2001. Vol. 73. Iss. 6. P. 673–683. https://doi.org/10.2175/106143001x143411Richard DE, Dwyer DF. Aerated biofiltration for simultaneous removal of iron and polycyclic aromatic hydrocarbons from groundwater. Water Environment Research. 2001;73(6):673–683. https://doi.org/10.2175/106143001x143411Groher D.M. An investigation of factors affecting the concentrations of polycyclic aromatic hydrocarbons in groundwater at coal tar waste sites. Cambridge: Massachusetts Institute of Technology, 1990. 145 p.Groher DM. An investigation of factors affecting the concentrations of polycyclic aromatic hydrocarbons in groundwater at coal tar waste sites. Cambridge: Massachusetts Institute of Technology; 1990. 145 p.Ilić P., Nešković Markić D., Stojanović Bjelić L. Evaluation of sources and ecological risk of PAHs in different layers of soil and groundwater // Preprints. 2020. https://doi.org/10.20944/preprints202002.0224.v1Ilić P, Nešković Markić D, Stojanović Bjelić L. Evaluation of sources and ecological risk of PAHs in different layers of soil and groundwater. Preprints. 2020. https://doi.org/10.20944/preprints202002.0224.v1Галицкая И.В., Позднякова И.А. К проблеме загрязнения подземных вод и пород зоны аэрации нефтепродуктами и ПАУ на городских территориях // Геоэкология. Инженерная геология. Гидрогеология. Геокриология. 2011. №. 4. С. 337–343.Galitskaya IV, Pozdnyakova IA. Contamination of groundwater and unsaturated zone deposits with oil products and PAH in urban areas. Geoekologiya. Inzhenernaya geologiya. Gidrogeologiya. Geokriologiya. 2011;4:337–343. (In Russ.)Mansilha C., Carvalho A., Guimarães P., Espinha Marques J. Water quality concerns due to forest fires: polycyclic aromatic hydrocarbons (PAH) contamination of groundwater from mountain areas // Journal of Toxicology and Environmental Health. Part A. 2014. Vol. 77. Iss. 14–16. P. 806–815. https://doi.org/10.1080/15287394.2014.909301Mansilha C, Carvalho A, Guimarães P, Espinha Marques J. Water quality concerns due to forest fires: polycyclic aromatic hydrocarbons (PAH) contamination of groundwater from mountain areas. Journal of Toxicology and Environmental Health. Part A. 2014;77(14–16):806– 815. https://doi.org/10.1080/15287394.2014.909301Sun Y., Zhang S., Lan J., Xie Z., Pu J., Yuan D., et al. Vertical migration from surface soils to groundwater and source appointment of polycyclic aromatic hydrocarbons in epikarst spring systems, southwest China // Chemosphere. 2019. Vol. 230. P. 616–627. https://doi.org/10.1016/j.chemosphere.2019.05.007Sun Y, Zhang S, Lan J, Xie Z, Pu J, Yuan D, et al. Vertical migration from surface soils to groundwater and source appointment of polycyclic aromatic hydrocarbons in epikarst spring systems, southwest China. Chemosphere. 2019;230:616–627. https://doi.org/10.1016/j.chemosphere.2019.05.007Liang M., Liang H., Rao Z., Xu D. Occurrence of polycyclic aromatic hydrocarbons in groundwater from rural areas in eastern China: spatial distribution, source apportionment and health cancer risk assessment // Chemosphere. 2020. Vol. 259. P. 127534. https://doi.org/10.1016/j.chemosphere.2020.127534Liang M, Liang H, Rao Z, Xu D. Occurrence of polycyclic aromatic hydrocarbons in groundwater from rural areas in eastern China: spatial distribution, source apportionment and health cancer risk assessment. Chemosphere. 2020;259:127534. https://doi.org/10.1016/j.chemosphere.2020.127534Туров Ю.П., Кадычагов П.Б., Гузняева М.Ю., Альшанский А.М. Полициклические ароматические углеводороды в подземных водах и почвах Обь-Томского междуречья // Химия в интересах устойчивого развития. 1999. №. 7. С. 291–299.Turov YuP, Kadychagov PB, Guznyaeva MYu, Al'shanskii AM. Polycyclic aromatic hydrocarbons in groundwater and soils of the Ob-Tomsk interfluve. Khimiya v interesakh ustoichivogo razvitiya. 1999;7:291–299. (In Russ.)Пиковский Ю.И. Природные и техногенные потоки углеводородов в окружающей среде: монография. М.: Изд-во МГУ, 1993. 208 с.Pikovskii YuI. Natural and technogenic flows of hydrocarbons in the environment. Moscow: Lomonosov Moscow State University; 1993. 208 p. (In Russ.)Хаустов А.П., Редина М.М., Яковлева Е.В. Водопроявления подземных вод как геохимические системообразующие объекты (интерпретация на основе распределения ПАУ) // Геоэкология. Инженерная геология. Гидрогеология. Геокриология. 2018. № 3. С. 3–17.Khaustov AP, Redina MM, Yakovleva EV. Groundwater sources as geochemical system-creating objects (interpretation based on PAH distribution). Geoekologiya. Inzhenernaya geologiya. Gidrogeologiya. Geokriologiya. 2018;3:3–17. (In Russ.)Хаустов А.П., Редина М.М. Парадоксы концентрирования углеводородов в компонентах геосистем (на примере ПАУ) // Сергеевские чтения: геоэкологические аспекты реализации национального проекта «Экология». Диалог поколений: материалы годичной сессии Научного совета РАН по проблемам геоэкологии, инженерной геологии и гидрогеологии. Вып. 22. М., 2020. С. 94–103.Khaustov AP, Redina MM. Paradoxes of hydrocarbons concentration in geosystem components (for the case of PAH). In: Sergeevskie chteniya: geoekologicheskie aspekty realizatsii natsional'nogo proekta “Ekologiya”. Dialog pokolenii: materialy godichnoi sessii Nauchnogo soveta RAN po problemam geoekologii, inzhenernoi geologii i gidrogeologii = Sergeevskie readings: geoecological aspects of the implementation of the national project "Ecology". Dialogue of generations: materials of the annual session of the Scientific Council of the Russian Academy of Sciences on the problems of geoecology, engineering geology and hydrogeology. Iss. 22. Moscow; 2020. p.94–103. (In Russ.)Khaustov A., Redina M., Goryainov S. Migration of PAHs and phthalates from package materials during water storage: glass or plastic? // Polycyclic Aromatic Compounds. 2020. P. 1–13. https://doi.org/10.1080/10406638.2020.1734033Khaustov A, Redina M, Goryainov S. Migration of PAHs and phthalates from package materials during water storage: glass or plastic? Polycyclic Aromatic Compounds. 2020;1–13. https://doi.org/10.1080/10406638.2020.1734033Schlanges I., Meyer D., Palm W.U., Ruck W. Identification, quantification and distribution of PAC-metabolites, heterocyclic PAC and substituted PAC in groundwater samples of tar-contaminated sites from Germany // Polycyclic Aromatic Compounds. 2008. Vol. 28. Iss. 4–5. P. 320– 338. https://doi.org/10.1080/10406630802377807Schlanges I, Meyer D, Palm WU, Ruck W. Identification, quantification and distribution of PAC-metabolites, heterocyclic PAC and substituted PAC in groundwater samples of tar-contaminated sites from Germany. Polycyclic Aromatic Compounds. 2008;28(4–5):320–338. https://doi.org/10.1080/10406630802377807Masih A., Lal J.K. Concentrations and carcinogenic profiles of polycyclic aromatic hydrocarbons (PAHs) in groundwater of an urban site at a Terai belt of North India // International Journal of Applied Engineering Research. 2014. Vol. 9. Iss. 1. P. 1–8.Masih A, Lal JK. Concentrations and carcinogenic profiles of polycyclic aromatic hydrocarbons (PAHs) in groundwater of an urban site at a Terai belt of North India. International Journal of Applied Engineering Research. 2014;9(1):1–8.Masih A., Saini R., Taneja A. Contamination and exposure profiles of priority polycyclic aromatic hydrocarbons (PAHs) in groundwater in a semi-arid region in India // International Journal of Water. 2008. Vol. 4. Iss. 1–2. P. 136–147. https://doi.org/10.1504/IJW.2008.018152Masih A, Saini R, Taneja A. Contamination and exposure profiles of priority polycyclic aromatic hydrocarbons (PAHs) in groundwater in a semi-arid region in India. International Journal of Water. 2008;4(1–2):136–147. https://doi.org/10.1504/IJW.2008.018152Kawka O.E.M. Hydrothermal alteration of sedimentary organic matter in Guaymas Basin, Gulf of California. Corvallis: Oregon State University, 1990. 236 p.Kawka OEM. Hydrothermal alteration of sedimentary organic matter in Guaymas Basin, Gulf of California. Corvallis: Oregon State University; 1990. 236 p.Khaustov A.P., Redina M.M. Indicator ratios of polycyclic aromatic hydrocarbons for geoenvironmental studies of natural and technogenic objects // Water Resources. 2017. Vol. 44. Iss. 7. P. 903–913. https://doi.org/10.1134/S0097807817070065Khaustov AP, Redina MM. Indicator ratios of polycyclic aromatic hydrocarbons for geoenvironmental studies of natural and technogenic objects. Water Resources. 2017;44(7):903–913. https://doi.org/10.1134/S0097807817070065Moyo S., McCrindle R., Mokgalaka N., Myburgh J., Mujuru M. Source apportionment of polycyclic aromatic hydrocarbons in sediments from polluted rivers // Pure and Applied Chemistry. 2013. Vol. 85. Iss. 12. P. 2175–2196. https://doi.org/10.1351/pac-con-12-10-08Moyo S, McCrindle R, Mokgalaka N, Myburgh J, Mujuru M. Source apportionment of polycyclic aromatic hydrocarbons in sediments from polluted rivers. Pure and Applied Chemistry. 2013;85(12):2175–2196. https://doi.org/10.1351/pac-con-12-10-08Soclo H.H., Garrigues P., Ewald M. Origin of polycyclic aromatic hydrocarbons (PAHs) in coastal marine sediments: case studies in Cotonou (Benin) and Aquitaine (France) areas // Marine Pollution Bulletin. 2020. Vol. 40. Iss. 5. P. 387–396. https://doi.org/10.1016/S0025-326X(99)00200-3Soclo HH, Garrigues P, Ewald M. Origin of polycyclic aromatic hydrocarbons (PAHs) in coastal marine sediments: case studies in Cotonou (Benin) and Aquitaine (France) areas. Marine Pollution Bulletin. 2020;40(5):387– 396. https://doi.org/10.1016/S0025-326X(99)00200-3Ţigănuş D., Coatu V., Lazăr L., Oros A., Spînu A.D. Identification of the sources of polycyclic aromatic hydrocarbons in sediments from the Romanian Black Sea sector // Revista Cercetări Marine. 2013. Vol. 43. Iss. 1. P. 187–196.Ţigănuş D, Coatu V, Lazăr L, Oros A, Spînu AD. Identification of the sources of polycyclic aromatic hydrocarbons in sediments from the Romanian Black Sea sector. Revista Cercetări Marine. 2013;43(1):187–196.

The authors declare that there are no conflicts of interest present.