MINERALIZATION AND METASOMATITES ZONING IN PORPHYRY COPPER DEPOSITS OF GOSHGARCHAI ORE MAGMATIC SYSTEM (LESSER CAUCASUS, AZERBAIJAN)
https://doi.org/10.21285/2541-9455-2018-41-1-38-53
Abstract
The Purpose of the paper is to analyze the zoning nature of mineralization and metasomatites in the known porphyry copper deposits of the Goshgarchai ore magmatic system (OMS) associated with the Murovdag group of intrusives.
The Methods used in the study include complex structural and geological, metallogenic, geological-petrological, ore metasomatic and petrochemical parameters of metasomatites as well as the studies that take into account science-based geological prospecting works carried out earlier. There is some regularity between the petrochemical parameters of metasomatites and the contents of copper and molybdenum.
Results. It has been found that the thickness of methasomatically altered rocks varies from several meters to tens and hundreds of meters (in the intersections of multi-oriented faults) within the Goshgarchai OMS. Their length ranges from 500-1000 m to 2000-3000 m. Three gradually changing each other elliptical metasomatic zones are distinguished around the ore generating intrusives of the Goshgarchai OMS. They border the intrusive massif of porphyry composition. The inner zone including the endocontact and apical parts of the porphyry intrusive is represented by strongly silicified rocks, which are almost completely transformed into secondary quartzirtes. The middle zone is determined as quartz-sericite-chlorite facies of secondary quartzirtes. The third external zone of the metasomatic column is represented by the propylite facies of secondary quartzirtes.
Conclusions. Having studied ore zoning within the borders of the Goshgarchai deposit we have obtained the following series of vertical zonality of elements (bottom-up): Mo→Cu→Со→Ni→Cr→Ag→Pb→Zn. Hydrothermal metasomatic variations of enclosing rocks in the zones of different types of metasomatites generated under deposit formation have been studied and compared on the basis of petrochemical data.
About the Authors
M. MansurovAzerbaijan
Associate Professor of the Department of Minerals Geology
tel.: +994506227175
23 Z. Halilov St., Baku AZ1148, Republic of Azerbaijan
M. Safari
Islamic Republic of Iran
Associate Professor of the Department of Minerals Geology
tel.: +989122889600
Artesh St., Tegeran, P.O. 19395-3697, Republic of Iran
B. Kalandarov
Azerbaijan
Professor of the Department of Hydrogeology and Engineering Geology
tel.: +994503428600
23 Z. Halilov St., Baku AZ1148, Republic of Azerbaijan
V. Kerimov
Azerbaijan
Associate Professor of the Department of General Geology
tel.: +994506151897
20 Azadlyg Ave., Baku AZ1010, Republic of Azerbaijan
A. Mamedova
Azerbaijan
Lecturer of the Department of Geochemistry and Mineralogy
tel.: +994503716146
23 Z. Halilov St., Baku AZ1148, Republic of Azerbaijan
References
1. Abdullaev R.N., Mustafaev G.V., Mustafaev M.A. Mezozoiskie magmaticheskie formatsii Malogo Kavkaza i svyazannoe s nimi endogennoe orudenenie [Mesozoic magmatic formations of the Lesser Caucasus and associated endogenous mineralization]. Baku: Elm Publ., 1988, 160 р. (In Russian).
2. Baba-zade V.M., Makhmudov A.I., Ramazanov V.G. Medno- i molibdenporfirovye mestorozhdeniya [Copper- and porphyry molybdenum deposits]. Baku: Azerneshr Publ., 1990, 377 р. (In Russian).
3. Ismail-zade A.D., Mustafaev G.V., Rustamov M.I. Geologiya Azerbaidzhana. Mag-matizm [Geology of Azerbaijan. Magmatism]. Baku: Nafta-Press Publ., 2001, vol. 32, 434 р. (In Russian).
4. Mansurov M.I. Models of oremagmatic systems of copper porphyry deposits of Goshgarchay ore field (Lesser Caucasus, Azerbaijan). Izvestiya Sibirskogo otdeleniya Sektsii nauk o Zemle Rossiiskoi akademii estestvennykh nauk. Geologiya, poiski i razvedka rudnykh mestorozhdenii [Proceedings of the Siberian Department of the Section of Earth Sciences, Russian Academy of Natural Sciences. Geology, Prospecting and Exploration of Ore Deposits], 2014, no. 4 (47), рр. 29–42. (In Russian).
5. Baba-zade V.M. Mineral'nosyr'evye resursy Azerbaidzhana (usloviya formirovaniya, zakonomernosti razmeshcheniya, nauchnye osnovy prognozirovaniya) [Azerbaijan mineral resources (formation conditions, location regularities, scientific bases of prediction)]. Baku: Ozan Publ., 2005, 808 р. (In Russian).
6. Reif F.G. Rudoobrazuyushchii potentsial granitov i usloviya ego realizatsii [Ore-forming potential of granites and its implementation conditions]. Moscow: Nauka Publ., 1990, 181 р. (In Russian).
7. Shikhalibeili E.Sh. Nekotorye problemnye voprosy geologicheskogo stroeniya i tektoniki Azerbaidzhana [Some problematic issues of Azerbaijan geological structure and tectonics]. Baku: Elm Publ., 1996, 215 р. (In Russian).
8. Krivtsov A.I. Geologicheskie osnovy prognozirovaniya i poiskov mednoporfirovykh mestorozhdenii [Geological bases for porphyry copper deposits forecasting and prospecting]. Moscow: Nedra Publ., 1983, 256 р. (In Russian).
9. Mansurov M.I. Geological and genetic model of Goshgarchai ore-magmatic system of Murovdag uplift (the Lesser Caucasus, Azerbaijan). Izvestiya Natsional'noi akademii nauk Azerbaidzhana. Nauki o Zemle [Azerbaijan National Academy of Sciences Proceedings. Earth Sciences], 2013, no. 4, рр. 16–22. (In Russian).
10. Mansurov M.I. Search and forecast criteria for identifying prospects and new types of mineralization of Murovdag horst-uplift. Vestnik Bakinskogo Universiteta. Seriya estestvennykh nauk [Baku University News. Natural Science series], 2013, no. 4, рр. 107–118. (In Russian).
11. Mongush A-D.O., Lebedev V.I. Ak-Sug copper-molibdenum-porphyry deposit: mineral composition of rocks and ores. Izvestiya Sibirskogo otdeleniya Sektsii nauk o Zemle Rossiiskoi akademii estestvennykh nauk. Geologiya, poiski i razvedka rudnykh mestorozhdenii [Proceedings of the Siberian Department of the Section of Earth Sciences, Russian Academy of Natural Sciences. Geology, Prospecting and Exploration of Ore Deposits], 2013, no. 1 (42), рр. 22–29. (In Russian).
12. Pavlova I.G., Sakhnovskii M.L. Models of ore magmatic systems of porphyry copper molybdenum deposits as a base for their search and prediction. Rudoobrazovanie i geneticheskie modeli endogennykh rudnykh formatsii [Ore genesis and genetic models of endogenous ore formations]. Novosibirsk: Nauka Publ., 1988, рр. 225–232. (In Russian).
13. Azadaliev Dzh.A. Features of porphyry copper ores of ore magmatic system of the Lesser Caucasus. Rudnomagmaticheskie sistemy orogennykh oblastei: materialy nauchnoi konferentsii, posvyashchennoi 90-letiyu I.Kh. Khamrabaeva [Ore-magmatic systems of orogenic areas. Materials of the scientific conference dedicated to the 90th birth anniversary of I.Kh. Khamrabaev]. Tashkent, 2010, рр. 304–308. (In Russian).
14. Ramazanov V.G., Kalandarov B.G., Khasaev A.I., Mansurov M.I., Mamedov Z.I., Takhmazova T.G. Geological and geophysical bases for endogenous mineralization prediction (on example of copper-porphyry deposits of the Lesser Caucasus). Gorno-geologicheskii zhurnal [Mining magazine], 2009, no. 1-2 (17-18), рр. 6–11. (In Russian).
15. Lowell J.D., Guilbert J.M. Lateral and vertical alteration-mineralization zoning in porphyry copper ore deposits. Economic Geology, 1970, vol. 65, рр. 373–408.
16. Berzina A.P., Dobretsov N.L., Sotnikov V.N. Evolution of copper molybdenum ore-magmatic systems of the Central Asian fold belt. Doklady Rossiiskoi akademii nauk [Doklady Earth Sciences], 1995, vol. 342, no. 1, pp. 73–75. (In Russian).
17. Sotnikov V.I., Berzina A.P., Kalinin A.S. Generalized genetic model of ore magmatic systems of copper-molybdenum ore clusters. Rudoobrazovanie i geneticheskie modeli endogennykh rudnykh formatsii [Ore genesis and genetic models of endogenous ore formations]. Novosibirsk: Nauka Publ., 1988, рр. 232–240. (In Russian).
18. Sillitoe R.H. Granites and metal deposits. Episodes, 1996, vol. 19, рр. 126–133.
19. Sillitoe R.H. Porphyry Copper Systems, Society of Economic Geologists, Inc. Economic Geology, 2010, vol. 105, рр. 3–41.
20. Sillitoe R.H., Hart S.R. Leadisotope signatures of porphyry copper deposits in oceanic and continental settings, Colombian Andes. Geochemical et Cosmochimica Acta, 1984, vol. 48, рр. 2135– 2142.
21. Sillitoe R.H. Gold-rich porphyry copper deposits: Geological model and exploration implications. Mineral deposit modeling: Geological Association of Canada / R.V. Kirkham, W.D. Sinclair, R.I. Thorpe, J.M. Duke, 1993, Special Paper 40, рр. 465–478.
22. Williams T.J., Candela P.A., Piccoli, P.M. The partitioning of copper between silicate melts and two phase aqueous fluids: An experimental investigation at 1 kbar, 800 °C and 0.5 kbar, 850 °C. Contributions to Mineralogy and Petrology, 1995, vol. 121, рр. 388–399.
23. Hedenquist J.W., Richards J. The influence of geochemical techniques on the development of genetic models for porphyry copper deposits, Techniques in Hydrothermal Ore Deposits Geology. Society of Economic Geology Short Course. Toronto, Canada, 24–25 October, 10/1998, рр. 235–256.
24. Reynolds T.J., Beane R.E. Evolution of hydrothermal fluid characteristics at the Santa Rita, New Mexico, porphyry copper deposit. Economic Geology, 1985, vol. 80, рр. 1328–1347.
25. Sheppard S.M.F., Nielsen R.L., Taylor H.P. Jr. Hydrogen and oxygen isotope ratios in minerals from porphyry copper deposits. Economic Geology, 1971, vol. 66, рр. 515–542.
26. Titli S.R., Bin R.E. Porphyry copper deposits. Genezis rudnykh mestorozhdenii [Genesis of ore deposits], vol. 1. Moscow: Mir Publ., 1984, рр. 245–333. (In Russian).
27. Omel'yanenko B.I. Okolorudnye gidrotermal'nye izmeneniya porod [Hydrothermal changes of wallrocks]. Moscow: Nedra Publ., 1978, 213 р. (In Russian).
Review
For citations:
Mansurov M., Safari M., Kalandarov B., Kerimov V., Mamedova A. MINERALIZATION AND METASOMATITES ZONING IN PORPHYRY COPPER DEPOSITS OF GOSHGARCHAI ORE MAGMATIC SYSTEM (LESSER CAUCASUS, AZERBAIJAN). Earth sciences and subsoil use. 2018;41(1):38-53. (In Russ.) https://doi.org/10.21285/2541-9455-2018-41-1-38-53